Therefore, it caused the resonant wavelength of the alloy nanodisk blueshifts. Moreover, the work function of Au/Ag composite is reported to monotonically decrease with
the increase of the Ag composition [34]. Based on a previous study [23], the work function will play a role on Ag/ZnO nanorods’ PL emission: with lower work function, the band alignments favor carriers to overcome the metal/ZnO interface barrier. This factor will further assist the PL emission enhancement in annealed Au/Ag nanodisk/ZnO nanorod system. Figure 6 Aligned ZnO nanorods and TEM image of Ag/Au nanodisks. (a) Aligned ZnO nanorods with PMMA-filled inter-space. Scale bar = 100 nm. (b) TEM image of Ag/Au nanodisks on top of ZnO nanorods. Scale bar = 100 nm. Figure 7 PL and absorption spectra of OSI-027 samples. (a) PL spectra under 325-nm laser excitation for samples annealed at 500°C, 550°C, and 600°C. (b) Absorption spectra for these samples. Conclusion In conclusion, Au and Ag hybrid nanodisk structures were formed on the top end BTSA1 solubility dmso surface of ZnO nanorods. By varying the rapid annealing temperatures, the composite nanodisks’ structure changed drastically. The core-shell and alloy Au/Ag nanodisks were achieved
and characterized, while their formation mechanisms were discussed. The composite nanodisks’ effect on tuning the ZnO nanorods’ PL properties was further carried out. It has been Cilengitide datasheet found that with higher annealing temperature the PL intensity from ZnO becomes stronger,
which is attributed to the shift of resonant wavelength due to composition change in the plasmonic nanodisks. Acknowledgements The authors thank the financial support from the National Science Foundation of China under the contract number 11204097. References 1. Mark D, Haeberle S, Roth G, Stetten FV, Zengerle R: Microfluidic lab-on-a-chip platforms: requirements, characteristics and applications. Chem Soc Re 2010, 39:1153–1182.CrossRef 2. Barth JV, Costantini G, Kern K: Engineering atomic and molecular nanostructures at surfaces. Nature 2005, 437:671–679.CrossRef 3. Alivisatos AP: Semiconductor clusters, nanocrystals, and quantum dots. Science 1996, 271:933–937.CrossRef 4. Yao J, Yan H, Lieber CM: A nanoscale combing technique for the large-scale assembly of highly aligned aminophylline nanowires. Nature Nanotechnol 2013, 8:329–335.CrossRef 5. Reed MA, Randall JN, Aggarwal RJ, Matyi RJ, Moore TM, Wetsel AE: Observation of discrete electronic states in a zero-dimensional semiconductor nanostructure. Phys Rev Lett 1988, 60:535–537.CrossRef 6. Kamat PV: Meeting the clean energy demand: nanostructure architectures for solar energy conversion. J Phys Chem C 2007, 111:2834–2860.CrossRef 7. Tao AR, Habas S, Yang PD: Shape control of colloidal metal nanocrystals. Small 2008, 4:310–325.CrossRef 8. Jain PK, Huang XH, El-Sayed IH, El-Sayed MA: Noble metals on the nanoscale: optical and photothermal properties and some applications in imaging, sensing, biology, and medicine.
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